NATIONAL TECHNICAL UNIVERSITY OF ATHENS
SCHOOL OF MINING AND METALLURGICAL ENGINEERING
Section of Metallurgy and Materials Technology
Laboratory of Metallurgy
 
HYDROMETALLURGY UNIT

 
 
Conclusions
 

Conclusions from the trial

1.    The nickel and cobalt recoveries achieved were around 60% and 36%, respectively

2.        Iron extraction was around 13%

3.    The ratio Fe/Ni in the leach liquor produced was 10/1, much lower than the value of this ratio in the ore, 49/1. Thus, the selectivity of the heap leaching technique for the phyllosilicate minerals over the iron minerals (haematite, goethite) is apparent and is due to the difference in the kinetics of dissolution of these minerals under the mild conditions of this technique

4.    Although agglomeration had not been performed, the percolation was good. However, it is believed that proper agglomeration in an agglomerator would certainly allow for higher flowrates to be used and thus shorter leaching times

5.    The sulphuric acid consumption was around 67kg H2SO4 /kg Ni. This is double the value that was usually obtained for many laterite samples leached by the N.T.U.A. Research Group. This high consumption was attributed to the high iron content of the ore chlorites and the high calcite content of the waste ore, that was used as a bedding layer

 

General Conclusions

1.    The pilot-scale heap leach test confirmed the leachability of the greek low –grade nickel oxide ore according to the HELLAS Method

2.    The main characteristic and advantage of the HELLAS Method is the selectivity of the nickel and cobalt leaching over iron at the mild conditions of the method (ambient temperature, dilute sulphuric acid solution)

3.    The most significant factor affecting the leachability of the nickel oxide ore, the recoveries of nickel and cobalt, the co- extraction of metal impurities and the sulphuric acid consumption is, besides the leaching conditions, the mineralogical composition of the ore. The higher the percentage of the ore nickel in the phyllosilicate minerals, the higher the nickel recovery. Also, the lower the iron and the magnesium contents of the phyllosilicate minerals, the lower the sulphuric acid consumption is. This is so because most of the iron and all of the magnesium and chromium pass into the solution from the phyllosilicate minerals.

4.    Given that in the majority of the greek nickel deposits, nickel occurs in phyllosilicate minerals, the HELLAS Method would allow the economic exploitation of poor nickel oxide ore deposits with nickel grade too low to be treated by any other method, pyrometallurgical or hydrometallurgical, whatsoever.